With Amazon buying MGM Films. It gives them access to the Bond movies. In association with Eon, they have the Bond IP.
In 007: Road to a Million they aim to exploit that with a high concept game show format that owes more to the BBC's Race Against the World. With added elements of Who Wants to be a Millionaire and The Apprentice.
Actor Brian Cox is the controller who is meant to be villainous. In the first episode he appears to be more of a friendly antagonist.
The first episode features the Bone brothers somewhere in the Scottish Highlands struggling to get an easy question right. Then they end up in Venice looking for a street then having to measure a snake!
They went further than the Pirmohamed sisters whose journey was a short one.
The Bond link was tenuous in the first episode consisting mainly of Bond music.
It is certainly a curiosity, it lacks the licence to thrill.