- Ni made her debut in Zhang Yimou's The Flowers of War, playing the lead female character "Yu Mo". Ni was eventually chosen, and became a new "Mou girl" like Gong Li and Zhang Ziyi.
- Ni was born in Nanjing, Jiangsu. She graduated from the Communication University of China, specializing in television broadcasting and hosting.
- A cat lover.
- Along with actresses Angelababy, Yang Mi and Liu Shishi, Ni Ni was chosen as the one of the New Four Dan Actresses in 2013.
- Ni Ni's zodiac animal is Dragon.
- Ni Ni won Best Actress award at the 21st Shanghai Film Critics Awards in 2012.
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