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- A rogue assassin returns to take down the secret organization that trained her.
- A Long Island farmer bands together a group of childhood friends to form an unlikely group of spies who turn the tide in America's fight for independence.
- A pair of hostage negotiators try to resist their budding attraction to each other.
- An FBI hostage negotiation team with a personal relationship try to work with a suicide bomber to release hostages and get him to stand down.
- After the team finds out a crime boss' daughter has been kidnapped, they have to use their skills on both another agent whose tap it was, and the father before starting things with the negotiator.
- An air traffic controller suspected in a mid-air collision takes the tower hostage, and Matt must find some way to get through to him before hundreds die in the planes he's preventing from landing.
- Emily and Matt end up sidelined in a negotiation when the HT will only talk to the first woman he spoke with, but her actions and demands put the operation at risk.
- Matt's ability to separate his feelings from the job are called into question when Emily is taken hostage.
- A man cheated out of an adoption takes a young girl hostage, and the team reluctantly works with an obstructive local shock jock to resolve the crisis.
- When an infamous sniper turns out to be a copycat, Matt and Emily try to draw the real shooter out before more people are killed.
- 17 year old Cary Steckler masterminds a plot to humiliate his high school tormentors (Andre, Chuck and Tina) by kidnapping them and "putting them on trial" live on the web, and Emily and Matt have to revert to younger versions of themselves (she the picked-on, he the bully) to get through the teens and prevent tragedy...
- A hostage situation at a hospital brings back memories for Matt that may complicate the negotiations.
- Matt and Emily cross the border unauthorized, tracking an escaped HT, but the tables are neatly turned when they find him and end up trapped.
- When a hostage becomes attached to Matt in the aftermath of her kidnapping, her claims of a stalker begin to worry Emily.
- When a cult leader abducts one of his followers and takes to the road, Matt and Emily's only chance to prevent an explosive outcome is to reach out to one of the members in the R.V.
- Two hostage crises split Matt and Emily: A train with too-knowledgeable HTs do a Houdini; and a schizophrenic patient breaks with reality, taking his doctor and her husband hostage.
- A young boy is abducted from the Santa Monica Pier.
- Dennis Ryker, key witness in a top level money laundering trial against Norris Burke, is kidnapped with his partner Lorraine, who is soon freed. The kidnapper's MO and knowledgeability indicate a security forces professional with torture experience. He demands millions 'for the dirty money to be recovered', or will kill Ryker. The FBI agent in charge of the money investigation is Cheryl Carrera's ex, Sam Weaver. Several players prove dirty, but who is in league with who?
- Californian juvenile prison riots are prevented by closing the institute and replacing it by an 'inhumane' state-of-the-art security facility. Murder-convicted lifer Jerome 'Rome' Kaden is violent towards the rookie guard Tony, but the leader of the inmate gang prevents the attack. Matt sympathizes with the sole demand - a televised hearing from senator Espinosa, and even digs into his past when he demands SWAT-type action. This may cost him his job and Emily. An unequal inmate bond also proves crucial.
- The CNU resolves a hostage situation when a corporate executive takes 16 hostages in the company's boardroom. A second crisis involves a domestic situation that results in Matt and Emily questioning a decision they had made during the earlier standoff.
- A Homeland Security customs agent (Fisk) tries to allow a container into the port of Los Angeles without inspection. Fisk takes three people hostage when the container is about to be searched, and the FBI steps in to negotiate. Meanwhile, Emily contemplates accepting a one-year assignment on a Special Task Force in Quantico that would mean being separated from Matt, who does not respond as she had hoped.
- Maddie, a bullied teen, receives help from a stranger online; Caspian, a teen loner and math genius, struggles with his parents' toxic relationship; Chanda, a computer engineer, secretly meets with a rival tech giant.
- When she was a deeply troubled teenager, Nikita was rescued from death row by a secret U.S. agency known only as Division, who trained her as a spy and assassin. Nikita was eventually betrayed by the only people she thought she could trust. Now, after three years in hiding, Nikita is seeking retribution and making it clear to her former boss, Percy and her former friends Michael and Birkhoff that she will stop at nothing to expose and destroy their covert operation. Division continues to recruit and train other young people, among them Jaden and Thom, erasing all evidence of their former lives and turning them into cold and efficient killers. One of these new recruits, Alex is a beautiful girl with a violent past and a story not so different from Nikita's. The recruits all spend part of their training with Amanda, a master manipulator who can turn any ugly duckling into a swan and any bleeding heart into a killer.
- Nikita rescues Jill, a journalist who is trying to expose a conspiracy involving Division and a major plane crash. Michael and Percy suspect Birkhoff of being Nikita's inside mole and send Amanda in to interrogate him. Michael enlists the help of the recruits, Alex, Jaden and Thom, to help them locate their latest target.
- Percy and Michael take their latest assignment, a Slavic leader wanted for war crimes, into protective custody. Nikita learns of their hideout and attempts to thwart their plan, but a mysterious group of mercenaries in search of nuclear material beats her to the task. Alex is activated earlier than expected for a special assignment that throws her into the crossfire of bullets. A flashback reveals a pivotal moment in Nikita's life.
- Nikita delves into her past when she posed as a nanny for an influential government official and decides to right the wrong of his death. During the mission, Michael comes to Nikita's rescue and begins to doubt Percy's motives. Back at Division, while undergoing basic training, Alex suffers from a panic attack which prompts Amanda to break her of claustrophobia.
- Division's secrets are at risk of being revealed when an operative becomes a fugitive.
- Nikita convinces Owen to trust her leading him to tell her how her fiancé died. The recruits transport vehicle is attacked and Alex and Thom are kidnapped (a division test). They are tortured and pushed to their limits until Alex breaks free and turns to Nikita for help.
- Alex alerts Nikita that a fellow recruit has been activated for a suicide mission.
- Nikita and Michael temporarily team-up to kill a terrorist who murdered Michael's family many years ago. When Percy learns this information, he sends Division agents to kill Nikita, who ultimately compromises the mission, leading to Michael's capture by the terrorist group. Alex is caught going through medical files inside Division so she creates a lie that involves Jaden and almost blows her cover.
- Division sends Thom to eliminate Anna, a woman who was having a secret affair with a U.S. Senator. Division agrees to cover up any trace of the affair as long as the Senator agrees to help pass a bill that will continue to fund the agency. Nikita, with Alex's help, attempts to reach out to Anna's parents, but the conversation doesn't go as she expected.
- Owen leaks secret information from Division's black boxes to the media, revealing that the U.S. Government was responsible for an assassination in Chile. As a result, Percy frames a C.I.A. agent, Ryan for the crime. Nikita and Owen go to Chile to rescue Ryan from mercenaries and in doing so end up getting captured. Nikita reveals the secrets of Division to Ryan in an effort to save all of their lives. Back inside Division, Alex spies on Percy and Birkhoff and witnesses a side to Percy she has never seen before.
- Alex informs Nikita that Division is sending her on her first mission to kill the leader of a crime syndicate. Alex is uneasy about taking someone's life but is reassured by Nikita who insists on helping her with the kill order. Birkhoff informs Percy and Michael when he discovers the shell program that a Division mole has been using to connect to Nikita in the outside world. When the mission doesn't go as planned, Nikita makes a quick decision in an effort to clear Alex's name. Inside Division, Jayden attempts to reveal Alex as the mole but Thom steps in and a shocking accident clears her name.
- Alex's first assignment is a group mission to kill the Prince of Georgia at a museum gala. After Alex tells Nikita about the order, the two devise a plan to foil the assassination. However, Nikita trusts the wrong person and their plans are foiled, resulting in a stand-off and alerting Division that Nikita is in the building. Percy sends Michael in to kill Nikita.
- Now an agent, Alex gets a new apartment and is given a cover job. She meets her new neighbor Nathan who invites her to a party at his house. Nikita warns Alex about getting too involved with people but Alex struggles between her duties at Division and living a normal life. Nikita realizes Division has implanted a kill chip in Alex's head and sets out to gain control of the chip. While interrogating Birkhoff, Nikita stuns Ryan by revealing a secret.
- Ryan intercepts a message about a dangerous cutting edge weapon coming into the U.S. so he asks Nikita to help him stop the delivery. Nikita discovers the man bringing the weapon into the country is Voss, a man she was forced to have a relationship with while undercover at Division. She reluctantly resumes her alter ego to retrieve the missile. Meanwhile, Michael interferes in Alex's new life with Nathan
- While out on a mission for Division, Alex runs into Irina, a woman from her past. Alex tries to help Irina break free from her captor, but her old friend double crosses her and turns Alex over to Vlad, a Russian mobster, with a debt to settle. Nikita realizes Alex is in trouble and sets out to save her but runs into Michael who is searching for his missing agent. Realizing she can't compromise Alex's secret, Nikita must find a way to work with Michael to save Alex without getting her friend killed by Division.
- In order to speed up her healing, Amanda sedates Alex after her last mission then takes advantage of Alex's drugged condition to question her about the secrets Amanda believes Alex is keeping. Nikita realizes Alex is in danger and tries to secure her another identity to smuggle her out of the country. However, Nikita's contact double-crosses her and she comes face to face with a surprising opponent. Meanwhile, Michael becomes suspicious of Alex and asks Birkhoff to investigate her.
- Michael confronts Nikita in her lair and reveals that he knows Alex is the mole. He tells Nikita that she has 24 hours to find Kasim, the man who killed Michael's family, or he will tell Percy about Alex.
- Owen returns with information on one of Percy's black boxes. Nikita returns to London with him to retrieve it but notices that Owen is acting strangely. Owen tells Nikita that he wants to release the contents of the black box and when Nikita disagrees, he turns on her. Meanwhile, Percy finds out Nikita is in London and dispenses Michael to kill her. Also, Amanda overhears Jaden arguing with Alex about the escape tunnels so she hooks Alex up to a lie detector to get the truth out of her once and for all.
- Nikita believes it's getting too dangerous for Alex at Division and decides its time Alex disappeared. Alex agrees but before the plan can be put in motion, she and Jaden are assigned to an overseas mission to stop the son of a foreign president from selling a newly developed nerve toxin. Things go awry and Alex must decide between saving the mission or saving herself.
- Frustrated that Nikita continues to intercept his black boxes, Percy sends Michael to check on one of the boxes and the guardian attached to it. Nikita makes it to the small Pennsylvania town first and is shocked to find that the guardian is a normal woman named Dana who has abandoned her post and is attempting to live a normal life with her husband and child. Tensions mount when Michael is forced to report Dana's actions and Division swarms in to clean up any evidence of her existence. Meanwhile, Alex and Jaden get into an argument and Nathan gets caught in the middle.
- After Michael learns that Percy has ordered Divison to kill anyone who could decrypt the black boxes, he sends Nikita in to save the last person on the list, a CIA cryptographer named Malcolm. Nikita kidnaps Malcolm and takes him to Ryan for protection. Meanwhile, Percy turns on Alex.
- Percy makes a move to take over the CIA, Alex goes rogue, and Michael gets trapped inside Division making him unable to help Nikita, who may have to pay with her life for helping Alex.
- Nikita and Michael plot to take down Division and Oversight and are prepared to use the contents of the black box to do so. Amanda is now running Division but Oversight has assigned one of their own, a new agent named Sean, to keep an eye on her. Amanda's first mission is to get back the black box from Nikita, and she enlists Alex's help to do so. Alex refuses until Amanda tells her she will help her find the man who killed Alex's father. Meanwhile, Nikita and Michael find help from an unlikely ally.
- While investigating an old corrupt Division program, P9, that seems to have resurfaced, Nikita and Michael run into Owen. He tells them he is searching for Dr. Joseph Mars, who is not only the mastermind behind P9, but also invented the Regimen and could help Owen wean himself off the dangerous drug. Michael is hesitant to trust Owen again but Nikita decides the three should join forces.
- Nikita is stunned when she hears that her old Division partner Kelly escaped from a Turkish prison. Nikita thought Kelly died years ago and always felt responsible because it happened on the mission where Nikita escaped from Division. Knowing Amanda will go after Kelly, Nikita tells Michael they have to go to Turkey to help her. Amanda sends Alex and Roan to Europe to stop the former partners from reuniting.
- Birkoff tells Nikita and Michael that a black box file reveals that an international terrorist named Ramon, who has been taking credit for some serious political assassinations, now works for Division. This news upsets Nikita since she was the agent that captured Ramon years ago and turned him over to Percy. Amanda convinces Alex to kill Anton Kochenko, a man who used to work for Alex's father, and plans to let Ramon take the credit for the murder. However, when Nikita disrupts Amanda's plan, Amanda fights back by taking what Nikita loves most.
- While searching for information on the black box, Birkoff (Aaron Stanford) stumbles upon Nikita's (Maggie Q) birth certificate. Nikita and Michael track down Nikita's father Richard (guest star David Keith), but the reunion is not quite what Nikita expected. Percy (Xander Berkeley) tells Alex (Lyndsy Fonseca) that the black box that Nikita has contains information that could help her avenge her father's death.
- Michael discovers Cassandra, a woman he once romanced under Division orders, is in danger. Feeling guilty for how things ended, he wants to help her but Nikita suspects there is more to it than easing his conscience. Amanda manipulates Alex into helping her on a mission but Sean gets caught in Amanda's web of lies and begins to doubt Division's true motives.